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North America 2018

20 \

World Cement

produced (Table 1). As of 2012, the cement had similar

global warming impacts to the European average and

significantly lower impacts than the US average. The

energy demand to produce the Roberta cement is higher

than for typical European cement but lower than for

typical US cement.

The plant further employs control devices and

control strategies to reduce criteria pollutants. The use

of alternative materials (flyash, lime kiln dust, and other

waste streams in the raw mix) fosters natural resource

conservation, while achieving the same clinker chemistry

as attained with otherwise mined natural materials.

CO

2

capture technology

Sustainable Energy Solutions (SES) offers a Cryogenic

Carbon Capture (CCC) process, wherein exhaust gas

is cooled until the CO

2

contained freezes.

6

SES has

been developing CCC since 2008. The separation and

liquefaction of CO

2

can be accomplished in a highly

energy efficient manner by cooling gases to the point

where CO

2

and other pollutants condense, then energy

is recovered, as the separated gas streams warm back to

near their original temperature.

The cryogenic approach saves additional energy over

other capture technologies by producing a liquid CO

2

stream directly, rather than producing a CO

2

gas that

must subsequently be compressed and liquefied. CCC

produces a pressurised liquid CO

2

stream at near room

temperature that is ready for downstream utilisation.

Heat exchange between the incoming and outgoing

gases provides nearly all the sensible heat (cooling

energy) required for this process. The compressors in

the process provide the additional energy for the CO

2

phase change and the separation of the CO

2

. Energy

required for pressure, compressor inefficiencies, heat

exchanger inefficiencies, and other minor decreases

further impact the energy requirements.

Potential advantages of CCC for integration into

cement plants include the following:

z

Minimal energy consumption (a projected

0.7 GJ/tonne CO

2

at full scale).

z

Significantly lower costs than incumbent CO

2

capture approaches (CAPEX estimated to be half

that of current amine technologies).

z

Retrofit to existing plants with no upstream

modification.

z

Removal of a variety of pollutants from the flue

gas (carbon dioxide, SO

X

, NO

X

, PM

XX

, mercury, and

arsenic).

z

Requires only electrical power and cooling water

with no need for steam or other plant resources.

The use of the CCC process in this project marked

the second occasion it was applied to cement plant CO

2

capture, following a previous 2014 trial at a western US

cement plant.

Argos Glenwood concrete plant

The captured CO

2

was used in the production of

concrete at the Argos ready-mixed concrete facility

in the Glenwood Park area of Atlanta, Georgia. The

operation has a throughput of 140 m

3

/hour of concrete

(Erie Strayer transit mix system) and typically ships

around 110 000 m

3

/year servicing the downtown

Atlanta area. The facility has been operating since 2007

and maintains certifications from the National Ready

Mixed Concrete Association (NRMCA) and Georgia

Department of Transportation. It is one of 460 plants

in the US recognised under the NRMCA Green-Star

Programme that identifies members who have achieved

environmental excellence.

CO

2

utilisation technology

CarbonCure’s CO

2

utilisation technology upcycles CO

2

,

sourced from final emitters, into concrete products to

achieve material performance, as well as environmental

and economic, advantages. The addition of CO

2

into

ready-mixed concrete as it is batched and mixed results

in its mineralisation as a nanoscale calcium carbonate.

The CO

2

utilisation can improve the compressive

strength by 10% or more, thereby enabling a producer

to optimise the materials used in the concrete mix.

7

As part of this mix optimisation, producers have the

opportunity to reduce cement content, yet achieve the

original specified strength. The technology is installed

and licensed to more than 80 ready-mixed concrete

producers across North America.

Demonstration details

Cement production

The Roberta plant production was monitored in terms

of clinker production and emissions characteristics

Table 1.

Summary and relative contributions of carbon and energy demand impacts from 1 kg of cement

production at Roberta.

Global warming potential

Energy demand

Aspect

kg CO

2e

Proportion

MJ

Proportion

Quarry and raw material

0.027

3%

0.364

8%

Calcination

0.473

57%

0

0%

Kiln operation

0.287

34%

3.67

78%

Cement grinding

0.049

6%

0.660

14%

Total

0.836

100%

4.69

100%